Acid-catalyzed pyrolytic synthesis of levoglucosan through salt-mediated ring locking-Reference-Cited by-同舟云学术

Acid-catalyzed pyrolytic synthesis of levoglucosan through salt-mediated ring locking

Published:2020 Issue:6 Volume:22 Page:1968-1977
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Chen Li¹²³⁴,Elias Welman C.¹²³⁴,Ben Yin Y.¹²³⁴,Conrad Zhang Z.⁵⁶⁷⁸,Wong Michael S.¹²³⁴⁹^ORCID

Affiliation:

1. Department of Chemical and Biomolecular Engineering

2. Rice University

3. Houston

4. USA

5. Dalian National Laboratory of Clean Energy

6. Dalian Institute of Chemical Physics

7. Dalian

8. China

9. Department of Chemistry

Abstract

The combination of Na₂SO₄/H₂SO₄ increases levoglucosan (LGA) yield from glucose pyrolysis from 6% to as high as 40%, as a result of sodium suppressing the opening of the glucose ring.

Funder

National Science Foundation

CAS-SAFEA International Partnership Program for Creative Research Teams

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/GC/C9GC03973B

Reference42 articles.

1. Fast Pyrolysis of Cellulose, Hemicellulose, and Lignin: Effect of Operating Temperature on Bio-oil Yield and Composition and Insights into the Intrinsic Pyrolysis Chemistry

2. Prospects for pyrolysis technologies in the bioenergy sector: A review

3. Unravelling the catalytic influence of naturally occurring salts on biomass pyrolysis chemistry using glucose as a model compound: a combined experimental and DFT study

4. Competing reactions limit levoglucosan yield during fast pyrolysis of cellulose

5. Production and purification of crystallized levoglucosan from pyrolysis of lignocellulosic biomass

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