Insights into the lithiation mechanism of CFx by a joint high-resolution 19F NMR, in situ TEM and 7Li NMR approach-Reference-Cited by-同舟云学术

Insights into the lithiation mechanism of CFx by a joint high-resolution 19F NMR, in situ TEM and 7Li NMR approach

Published:2019 Issue:34 Volume:7 Page:19793-19799
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Zhong Guiming¹²³⁴⁵^ORCID,Chen Huixin¹²³⁴⁵^ORCID,Cheng Yong⁶⁷⁸⁵,Meng Lingyi¹²³⁴⁵^ORCID,Liu Haodong⁹¹⁰¹¹,Liu Zigeng¹²¹³¹⁴^ORCID,Zheng Guorui¹⁵¹⁶¹⁷⁷⁸,Xiang Yuxuan¹⁵¹⁶¹⁷⁷⁸,Liu Xiangsi¹⁵¹⁶¹⁷⁷⁸,Li Qi¹⁵¹⁶¹⁷⁷⁸,Zhang Qiaobao⁶⁷⁸⁵^ORCID,Yue Hongjun¹²³⁴⁵,Lu Canzhong¹²³⁴⁵^ORCID,Yang Yong¹⁵¹⁶¹⁷⁷⁸

Affiliation:

1. CAS Key Laboratory of Design and Assembly of Functional Nanostructures

2. Fujian Provincial Key Laboratory of Nanomaterials

3. Fujian Institute of Research on the Structure of Matter

4. Chinese Academy of Sciences

5. China

6. Department of Materials Science and Engineering

7. Xiamen University

8. Xiamen 361005

9. Department of Nanoengineering

10. University of California San Diego

11. USA

12. Max-Planck-Institut für Chemische Energiekonversion

13. 45470 Mülheim an der Ruhr

14. Germany

15. State Key Lab of Physical Chemistry of Solid Surfaces

16. Collaborative Innovation Center of Chemistry for Energy Materials

17. Department of Chemistry

Abstract

Lithiation reaction mechanism of CFx is revealed, determining that the fluorinated carbon with low fluorination level is produced along with carbon and LiF. Furthermore, the nucleation and growth processes of formed LiF are illustrated.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Natural Science Foundation of Fujian Province

Fujian Institute of Research on the Structure of Matter

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/TA/C9TA06800G

Reference29 articles.