Rh(i)-Catalyzed stereoselective intramolecular cycloaddition reactions of ene-vinylidenecyclopropanes for the construction of fused 6,5-bicyclic skeletons with a quaternary all-carbon stereocenter-Reference-Cited by-同舟云学术

Rh(i)-Catalyzed stereoselective intramolecular cycloaddition reactions of ene-vinylidenecyclopropanes for the construction of fused 6,5-bicyclic skeletons with a quaternary all-carbon stereocenter

Published:2019 Issue:14 Volume:6 Page:2506-2513
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Rui Kang-Hua¹²³⁴⁵,Yang Song¹²³⁴⁵,Wei Yin⁶⁷⁸⁹¹⁰^ORCID,Shi Min¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory for Advanced Materials and Institute of Fine Chemicals

2. School of Chemistry & Molecular Engineering

3. East China University of Science and Technology

4. Shanghai

5. China

6. State Key Laboratory of Organometallic Chemistry

7. Center for Excellence in Molecular Synthesis

8. University of Chinese Academy of Science

9. Shanghai Institute of Organic Chemistry

10. Chinese Academy of Sciences

Abstract

Rh(i)-catalyzed asymmetric [3 + 2] cycloadditions of ene-VDCPs are demonstrated, producing cyclic ring structures with an all-carbon quaternary stereocenter in good yields with excellent enantioselectivities.

Funder

National Basic Research Program of China

Chinese Academy of Sciences

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00611G

Reference96 articles.