Insights into the kinetics and molecular mechanism of the Newman–Kwart rearrangement-Reference-Cited by-同舟云学术

Insights into the kinetics and molecular mechanism of the Newman–Kwart rearrangement

Published:2021 Issue:36 Volume:45 Page:16978-16988
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Sanie Mitra¹^ORCID,Zahedi Ehsan²^ORCID,Ghorbani Seyed Hosein¹,Seif Ahmad³^ORCID

Affiliation:

1. Department of Chemistry, Borujerd Branch, Islamic Azad University, Borujerd, Iran

2. Department of Chemistry, Herbal Medicines Raw Materials Research Center, Shahrood Branch, Islamic Azad University, Shahrood, Iran

3. Department of Chemistry, Central Tehran Branch, Islamic Azad University, Tehran, Iran

Abstract

Kinetics and molecular mechanism of the Newman–Kwart rearrangement (NKR) of N,N-dimethyl O-arylthiocarbamate into N,N-dimethyl S-arylcarbamate have been investigated theoretically.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D1NJ02966E

Reference52 articles.

1. Iron(II)/Persulfate Mediated Newman–Kwart Rearrangement

2. The Conversion of Phenols to Thiophenols via Dialkylthiocarbamates1

3. The Vapor Phase Rearrangement of Thioncarbonates and Thioncarbamates

4. Quantum Chemical Characterization of Factors Affecting the Neutral and Radical-Cation Newman–Kwart Reactions

5. Inverting the Selectivity of the Newman–Kwart Rearrangement via One Electron Oxidation at Room Temperature

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