Crystallization kinetics of cerium oxide nanoparticles formed by spontaneous, room-temperature hydrolysis of cerium(iv) ammonium nitrate in light and heavy water-Reference-Cited by-同舟云学术

Crystallization kinetics of cerium oxide nanoparticles formed by spontaneous, room-temperature hydrolysis of cerium(iv) ammonium nitrate in light and heavy water

Published:2017 Issue:5 Volume:19 Page:3523-3531
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Pettinger Natasha W.¹²³⁴,Williams Robert E. A.⁵⁶⁷⁸⁴,Chen Jinquan¹²³⁴,Kohler Bern¹²³⁴¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. Montana State University

3. Bozeman

4. USA

5. Center for Electron Microscopy and Analysis

6. Department of Materials Science and Engineering

7. Ohio State University

8. Columbus

Abstract

Ceria nanocrystals form tenfold more slowly in D₂O vs. H₂O, revealing a rate-determining proton transfer reaction and a non-classical crystallization mechanism.

Funder

American Chemical Society Petroleum Research Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C6CP08227K

Reference42 articles.

1. Prenucleation clusters and non-classical nucleation

2. Crystallization by particle attachment in synthetic, biogenic, and geologic environments

3. Theory, Production and Mechanism of Formation of Monodispersed Hydrosols