Conduction transition and electronic conductivity enhancement of cesium azide by pressure-directed grain boundary engineering

Author:

Wang Qinglin12345ORCID,Wang Xiaofeng12345,Li Jianfu6785,Qin Tianru91011125,Sang Dandan12345,Liu Jiaoli12345,Ke Feng13141516,Wang Xiaoli6785,Li Yinwei12345,Liu Cailong12345ORCID

Affiliation:

1. Shandong Key Laboratory of Optical Communication Science and Technology

2. School of Physics Science & Information Technology

3. Liaocheng University

4. Liaocheng 252059

5. China

6. School of Opto-Electronic Information Science and Technology

7. Yantai University

8. Yantai 264005

9. Heilongjiang Province Key Laboratory of Superhard Materials

10. Physics Department

11. Mudanjiang Normal University

12. Mudanjiang 157012

13. Department of Geological Sciences

14. Stanford University

15. Stanford

16. USA

Abstract

Pressure induces a transition from mixed ionic–electronic conduction to pure electronic conduction in CsN3. The grain boundary effect improves the conductivity of CsN3 by more than two orders of magnitude after one pressure cycle.

Funder

Natural Science Foundation of Shandong Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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