Robust and efficient transfer hydrogenation of carbonyl compounds catalyzed by <i>NN</i>-Mn(<scp>i</scp>) complexes-Reference-Cited by-同舟云学术

Robust and efficient transfer hydrogenation of carbonyl compounds catalyzed by NN-Mn(i) complexes

Published:2023 Issue:30 Volume:52 Page:10574-10583
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wang Zheng¹²³^ORCID,Ma Ning¹,Lu Xiaochi¹,Liu Ming²^ORCID,Liu Tian²,Liu Qingbin³^ORCID,Solan Gregory A.²⁴,Sun Wen-Hua²^ORCID

Affiliation:

1. College of Science, Hebei Agricultural University, Baoding 071001, China

2. Key Laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

3. Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang 050024, China

4. Department of Chemistry, University of Leicester, University Road, Leicester LE1 7RH, UK

Abstract

A robust NN-manganese(i) complex has been developed that can efficiently catalyze the TH of a broad range of carbonyl derivatives to their corresponding alcohols with TON's and TOF's as high as 17 200 and TOF of 3550 h−1, respectively.

Funder

Natural Science Foundation of Hebei Province

Chinese Academy of Sciences

Hebei Agricultural University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02022C

Reference90 articles.

1. P. G.Andersson and I. J.Munslo , in Modern Reduction Methods , Wiley , New York , 2008