Generation of Ru(<scp>iii</scp>)-hypochlorite with resemblance to the heme-dependent haloperoxidase enzyme-Reference-Cited by-同舟云学术

Generation of Ru(iii)-hypochlorite with resemblance to the heme-dependent haloperoxidase enzyme

Published:2023 Issue:35 Volume:52 Page:12552-12559
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kumar Rakesh¹,Ahsan Faiza²^ORCID,Awasthi Ayushi¹,Swart Marcel²³^ORCID,Draksharapu Apparao¹^ORCID

Affiliation:

1. Southern Laboratories - 208A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur-208016, India

2. IQCC & Departament de Química, Universitat de Girona, 17003 Girona, Spain

3. ICREA, 08010, Barcelona, Spain

Abstract

The reaction of (Me/BnTPEN)RuII with mCPBA in the presence of Cl− ions generated a novel (Me/BnTPEN)RuIII–OCl species at RT. This study mimics the synthesis of a MIII–OCl adduct in a similar fashion as in the heme dependent haloperoxidase enzyme.

Funder

Indian Institute of Technology Kanpur

CSIR - Indian Institute of Chemical Biology

Departament d'Innovació, Universitats i Empresa, Generalitat de Catalunya

Science and Engineering Research Board

Agencia Estatal de Investigación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02028B

Reference41 articles.

1. Positron Emission Tomography (PET) radiotracers in oncology – utility of 18F-Fluoro-deoxy-glucose (FDG)-PET in the management of patients with non-small-cell lung cancer (NSCLC)

2. N3-Substituted thymidine analogues V: Synthesis and preliminary PET imaging of N3-[18F]fluoroethyl thymidine and N3-[18F]fluoropropyl thymidine

3. PET Molecular Imaging in Drug Development: The Imaging and Chemistry Perspective

4. Imaging proliferation in vivo with [F-18]FLT and positron emission tomography

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis and characterization of copper(ii) complexes: their catalytic behavior towards alcohol oxidation using NaOCl as the oxidant;New Journal of Chemistry;2024