Surface reactions of ammonia on ruthenium nanoparticles revealed by 15N and 13C solid-state NMR-Reference-Cited by-同舟云学术

Surface reactions of ammonia on ruthenium nanoparticles revealed by 15N and 13C solid-state NMR

Published:2021 Issue:13 Volume:11 Page:4509-4520
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Rothermel Niels¹²³⁴,Limbach Hans-Heinrich⁵⁶⁷⁴^ORCID,del Rosal Iker⁸⁹¹⁰¹¹¹²^ORCID,Poteau Romuald⁸⁹¹⁰¹¹¹²^ORCID,Mencia Gabriel⁸⁹¹⁰¹¹¹²^ORCID,Chaudret Bruno⁸⁹¹⁰¹¹¹²^ORCID,Buntkowsky Gerd¹²³⁴^ORCID,Gutmann Torsten¹²³⁴^ORCID

Affiliation:

1. Technical University of Darmstadt

2. Institute of Inorganic and Physical Chemistry

3. D-64287 Darmstadt

4. Germany

5. Free Universität of Berlin

6. Institute of Chemistry and Biochemistry

7. D-14195 Berlin

8. LPCNO

9. INSA-CNRS-UPS

10. Institut National des Sciences Appliquées

11. Université de Toulouse

12. 31077 Toulouse

Abstract

Ruthenium nanoparticles (Ru NPs) stabilized by bis-diphenylphosphinobutane (dppb) and surface-saturated with hydrogen have been exposed to gaseous ¹⁵NH₃ and ¹³CO and studied using solid-state NMR and DFT calculations.

Funder

Deutsche Forschungsgemeinschaft

Horizon 2020

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D0CY02476G

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