Avoided spin coupling: an unexpected σ–σ diradical in global planar pentacoordinate carbon-Reference-Cited by-同舟云学术

Avoided spin coupling: an unexpected σ–σ diradical in global planar pentacoordinate carbon

Published:2020 Issue:53 Volume:56 Page:7285-7288
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wang Meng-hui¹²³⁴,Dong Xue¹²³⁴,Ding Yi-hong⁵⁶⁷⁸⁹^ORCID,Cui Zhong-hua¹²³⁴^ORCID

Affiliation:

1. Institute of Atomic and Molecular Physics

2. Jilin University; Beijing National Laboratory for Molecular Sciences

3. Changchun 130012

4. China

5. Key Laboratory of Carbon Materials of Zhejiang Province

6. College of Chemistry and Materials Engineering

7. Wenzhou University

8. Wenzhou 325035

9. P. R. China

Abstract

We present a global planar pentacoordinate carbon (ppC) featuring a hitherto unreported σ–σ diradical characteristic.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC02236E

Reference50 articles.

1. Planar tetracoordinate carbon

2. A new, general strategy for achieving planar tetracoordinate geometries for carbon and other second row periodic elements

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