Facile synthesis of α-trifluoromethylthio phosphonium ylides with a constrained trifluoromethylthiooxide via a proton-transfer procedure-Reference-Cited by-同舟云学术

Facile synthesis of α-trifluoromethylthio phosphonium ylides with a constrained trifluoromethylthiooxide via a proton-transfer procedure

Published:2019 Issue:64 Volume:55 Page:9479-9482
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Cao Chengyao Kimmy¹²³⁴⁵,Zhang Yue⁶⁷⁸⁵,Lan Tianlei⁶⁷⁸⁵,Liu Wei⁹⁷⁸⁵,Chen Chao¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education)

2. Department of Chemistry

3. Tsinghua University

4. Beijing 100084

5. China

6. College of Chemical Engineering and Materials Science

7. Tianjin University of Science & Technology

8. Tianjin

9. College of Sciences

Abstract

Synthesis of α-trifluoromethylthio(CF₃S–)phosphonium ylides is easily accomplished with a constrained trifluoromethylthiooxide via a proton-transfer procedure without extra base.

Funder

Fok Ying Tong Education Foundation

National Natural Science Foundation of China

National Basic Research Program of China

Department of Education of Guangdong Province

Wuyi University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC04234B

Reference84 articles.

1. Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept

2. Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

3. Shelf-Stable Electrophilic Reagents for Trifluoromethylthiolation

4. Late stage trifluoromethylthiolation strategies for organic compounds

5. State-of-the-Art in Electrophilic Trifluoromethylthiolation Reagents

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