Structural and spectroscopic characterizations of new Cd1−3xNd2x□xMoO4scheelite-type molybdates with vacancies as potential optical materials

Author:

Guzik M.1234,Tomaszewicz E.5674,Guyot Y.89101112,Legendziewicz J.1234,Boulon G.89101112

Affiliation:

1. Faculty of Chemistry

2. University of Wroclaw

3. 50-383 Wroclaw

4. Poland

5. Department of Inorganic and Analytical Chemistry

6. West Pomeranian University of Technology

7. 71-065 Szczecin

8. Institute Light Matter (ILM)

9. UMR5306 CNRS-University Lyon1

10. University of Lyon

11. 69622 Villeurbanne

12. France

Abstract

Spectroscopic analysis of Nd3+in Cd1−3xNd2xxMoO4points out two non-equivalent symmetry sites depending on the location of the □ vacancies. Both short lifetimes and high emission intensities suggest that the compounds could be especially promising for an ultra-short pulse laser generation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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