Thermodynamic and spectroscopic study on the solvation and complexation behavior of Ln(iii) in ionic liquids: binding of Ln(iii) with CMPO in C4mimNTf2-Reference-Cited by-同舟云学术

Thermodynamic and spectroscopic study on the solvation and complexation behavior of Ln(iii) in ionic liquids: binding of Ln(iii) with CMPO in C4mimNTf2

Published:2018 Issue:11 Volume:42 Page:9098-9109
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Wu Wenchao¹²³⁴⁵,Sun Taoxiang¹²³⁴⁵^ORCID,Pu Ning¹²³⁴⁵,Meng Dechao¹²³⁴⁵,Li Youzhen¹²³⁴⁵,Dang Jiahao¹²³⁴⁵,Yang Ying⁶⁷⁴⁵,Chen Jing¹²³⁴⁵,Xu Chao¹²³⁴⁵^ORCID

Affiliation:

1. Collaborative Innovation Center of Advanced Nuclear Energy Technology

2. Institute of Nuclear and New Energy Technology

3. Tsinghua University

4. Beijing

5. China

6. State Key Laboratory of Heavy Oil Processing

7. China University of Petroleum

Abstract

Thermodynamics of Ln(iii) complexation with CMPO in “dry” and “wet” ionic liquids reflects how solvation of Ln(iii) affects the complexation and helps identify the extractive species involved in solvent extraction.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ00344K

Reference66 articles.

1. Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2

2. Ionic Liquids-Based Extraction: A Promising Strategy for the Advanced Nuclear Fuel Cycle

3. Liquid–liquid extraction of actinides, lanthanides, and fission products by use of ionic liquids: from discovery to understanding