Organocatalytic allylic alkylation of alkyne-substituted MBH carbonates: access to quaternary carbon-containing 1,4-enynes-Reference-Cited by-同舟云学术

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Organocatalytic allylic alkylation of alkyne-substituted MBH carbonates: access to quaternary carbon-containing 1,4-enynes

Published:2023 Issue:41 Volume:21 Page:8263-8266
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Li Yu¹,Wang Mei¹,Ma Rongrong¹,Niu Rui¹,Wang Haodong¹,Zhang Yantu¹,Lin Jun-Bing¹^ORCID

Affiliation:

1. Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an 716000, China

Abstract

A DABCO-catalyzed allylic alkylation of alkyne-substituted MBH carbonates with nitromethane was realized, delivering a series of all-carbon quaternary center-containing 1,4-enynes.

Funder

Natural Science Basic Research Program of Shaanxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D3OB01317K

Reference44 articles.

1. Prostaglandin analogs possessing antinidatory effects. 1. Modification of the .omega. chain

2. Antimutagenic Activity of Falcarindiol from Peucedanum praeruptorum

3. Investigation of the Antioxidant Activity of African Potato (Hypoxis hemerocallidea)

4. Copper(I)-Catalyzed Enantioselective Addition of Enynes to Ketones

5. Combining NHC-Cu and Brønsted Base Catalysis: Enantioselective Allylic Substitution/Conjugate Additions with Alkynylaluminum Reagents and Stereospecific Isomerization of the Products to Trisubstituted Allenes

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