Organocatalytic allylic alkylation of alkyne-substituted MBH carbonates: access to quaternary carbon-containing 1,4-enynes

Author:

Li Yu1,Wang Mei1,Ma Rongrong1,Niu Rui1,Wang Haodong1,Zhang Yantu1,Lin Jun-Bing1ORCID

Affiliation:

1. Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an 716000, China

Abstract

A DABCO-catalyzed allylic alkylation of alkyne-substituted MBH carbonates with nitromethane was realized, delivering a series of all-carbon quaternary center-containing 1,4-enynes.

Funder

Natural Science Basic Research Program of Shaanxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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