Mechanistic insight of TiCl4catalyzed formal [3 + 3] cyclization of 1,3-bis(silyl enol ethers) with 1,3-dielectrophiles-Reference-Cited by-同舟云学术

Mechanistic insight of TiCl4catalyzed formal [3 + 3] cyclization of 1,3-bis(silyl enol ethers) with 1,3-dielectrophiles

Published:2015 Issue:114 Volume:5 Page:94304-94314
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Nisa Riffat Un¹²³⁴⁵,Maria Maria¹²³⁴⁵,Wasim Fatima¹²³⁴⁵,Mahmood Tariq¹²³⁴⁵,Ludwig Ralf⁶⁷⁸⁹¹⁰,Ayub Khurshid¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. COMSATS Institute for Information Technology

3. Campus Abbottabad

4. Abbottabad

5. Pakistan

6. Leibniz-Institut für Katalyse e. V. an der Universität Rostock

7. 18059 Rostock

8. Germany

9. Department of Physical Chemistry

10. University of Rostock

Abstract

The mechanism of TiCl₄mediated formal [3 + 3] cyclization of 1,3-bis(silyl enol ethers) with 1,3-dielectrophiles is studied at the B3LYP level of density functional theory (DFT) to rationalize the experimental regioselectivity.

Funder

Higher Education Commission, Pakistan

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA19238B

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