Formation of a stable radical by oxidation of a tetraorganoborate-Reference-Cited by-同舟云学术

Formation of a stable radical by oxidation of a tetraorganoborate

Published:2016 Issue:43 Volume:52 Page:7005-7008
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Braunschweig Holger¹²³⁴,Krummenacher Ivo¹²³⁴,Mailänder Lisa¹²³⁴,Pentecost Leanne⁵⁶⁷⁸⁹,Vargas Alfredo⁵⁶⁷⁸⁹

Affiliation:

1. Institut für Anorganische Chemie

2. Julius-Maximilians-Universität Würzburg

3. 97074 Würzburg

4. Germany

5. Department of Chemistry

6. School of Life Sciences

7. University of Sussex

8. Brighton BN1 9QJ

9. UK

Abstract

Oxidation of a tetraorganoborate salt leads to selective formation of the corresponding zwitterionic radical rather than carbon–carbon bond formation of the boron substituents.

Funder

University Of Sussex

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC02916G

Reference37 articles.

1. The Electroöxidation of the Tetraphenylborate Ion; An Example of a Secondary Chemical Reaction Following the Primary Electrode Process

2. EVIDENCE FOR THE FORMATION OF BIPHENYL BY INTRAMOLECULAR DIMERIZATION IN THE ELECTROÖXIDATION OF TETRAPHENYLBORATE ION

3. Tetraarylborates {[Ar]4B-}: estimation of oxidation potentials and reorganization energies from electron-transfer rates

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