Selective telomerisation of isoprene with methanol by a heterogeneous palladium resin catalyst-Reference-Cited by-同舟云学术

Selective telomerisation of isoprene with methanol by a heterogeneous palladium resin catalyst

Published:2015 Issue:2 Volume:5 Page:1206-1212
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Torrente-Murciano Laura¹²³⁴,Nielsen David⁵⁶⁷⁴,Jackstell Ralf⁸⁹¹⁰,Beller Matthias⁸⁹¹⁰,Cavell Kingsley⁵⁶⁷⁴,Lapkin Alexei A.¹¹¹²¹³⁴

Affiliation:

1. Department of Chemical Engineering

2. University of Bath

3. Bath BA2 7AY

4. UK

5. Department of Chemistry

6. University of Cardiff

7. Cardiff CF10 3AT

8. Leibniz-Institut für Organische Katalyse an der Universität Rostock e.V.

9. 18055 Rostock

10. Germany

11. Department of Chemical Engineering and Biotechnology

12. University of Cambridge

13. Cambridge CB2 3RA

Abstract

A heterogeneous (DVB-resin-PPh₃-Pd-dvds) catalyst presents high activity for the telomerization of isoprene with methanol with an unsusual regioselectivity towards tail-to-tail telomerization products.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CY/C4CY01320D

Reference45 articles.

1. Oligomerization and dimerization of butadiene under homogeneous catalysis. Reaction with nucleophiles and the synthesis of 1,3,7-octatriene

2. The dimerization of butadiene by palladium complex catalysts

3. Bulk and fine chemicals via aqueous biphasic catalysis

4. Telomerization: Advances and Applications of a Versatile Reaction

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