Selective synthesis and reactivity expansion of α,β-unsaturated geminal diazides-Reference-Cited by-同舟云学术

Selective synthesis and reactivity expansion of α,β-unsaturated geminal diazides

Published:2022 Issue:8 Volume:9 Page:2116-2120
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Chen Chen¹,Ge Jun¹,He Ling¹^ORCID

Affiliation:

1. Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, Sichuan Engineering Laboratory for Plant-Sourced Drug and Sichuan Research Center for Drug Precision Industrial Technology, Department of Medicinal Chemistry, West China School of Pharmacy, Sichuan University, Chengdu, Sichuan, 610041, P. R. China

Abstract

α,β-Unsaturated gem-diazides were selectively obtained catalyzed by Yb(TfO)3 using α,β-unsaturated aldehydes as substrates and TMSN3 as a nitrogen source under mild and simple conditions in moderate yields without Schmidt and allylic rearrangement.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO00008C

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