The full dynamics of energy relaxation in large organic molecules: from photo-excitation to solvent heating

Author:

Balevičius Jr Vytautas1234ORCID,Wei Tiejun1234,Di Tommaso Devis1234ORCID,Abramavicius Darius5678ORCID,Hauer Jürgen910111213,Polívka Tomas1415161718,Duffy Christopher D. P.1234ORCID

Affiliation:

1. School of Chemical and Biological Sciences

2. Queen Mary University of London

3. London E1 4NS

4. UK

5. Institute of Chemical Physics

6. Vilnius University

7. Vilnius

8. Lithuania

9. Fakultät für Chemie

10. Technical University of Munich

11. D-85748 Garching

12. Germany

13. Photonics Institute

14. Institute of Physics and Biophysics

15. Faculty of Science

16. University of South Bohemia

17. 37005 České Budějovice

18. Czech Republic

Abstract

In some molecular systems, such as nucleobases, polyenes or sunscreens, substantial amounts of photo-excitation energy are dissipated on a sub-picosecond time scale. Where does this energy go or among which degrees of freedom it is being distributed at such early times?

Funder

Austrian Science Fund

Deutsche Forschungsgemeinschaft

Grantová Agentura České Republiky

Leverhulme Trust

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference71 articles.

1. Ultrafast Photochemistry in Liquids

2. Ultrafast Elementary Photochemical Processes of Organic Molecules in Liquid Solution

3. Proteins: Energy, Heat and Signal Flow , ed. D. M. Leitner and J. E. Straub , CRC Press , 2009

4. D. M. Leitner , in Energy Relaxation and Thermal Transport in Molecules , ed. W. Andreoni and S. Yip , Springer International Publishing , 2018 , pp. 1–22

5. Energy Disposition in Reactive Intermediates

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