Mechanistic study on –C–O– and –C–C– hydrogenolysis over Cu catalysts: identification of reaction pathways and key intermediates-Reference-Cited by-同舟云学术

Mechanistic study on –C–O– and –C–C– hydrogenolysis over Cu catalysts: identification of reaction pathways and key intermediates

Published:2018 Issue:3 Volume:8 Page:755-767
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Kühne Benjamin¹²³⁴,Vogel Herbert¹²³⁴,Meusinger Reinhard⁵²³⁴,Kunz Sebastian⁶⁷⁸⁴^ORCID,Kunz Markwart¹²³⁴

Affiliation:

1. Institute for Technical and Macromolecular Chemistry

2. TU Darmstadt

3. D-64287 Darmstadt

4. Germany

5. Institute for Organic Chemistry and Biochemistry

6. Institute for Applied and Physical Chemistry

7. University of Bremen

8. D-28359 Bremen

Abstract

Sugar alcohols are found to adsorb over Cu catalysts via two vicinal OH-groups, forming a chelate complex with selective –C–O– bond cleavage of adjacent free OH-groups. Different side reactions via unsaturated intermediates on the catalyst surface yield C1 to C5 polyols.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CY/C7CY02426F

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