Vanadium(v) oxoanions in basic water solution: a simple oxidative system for the one pot selective conversion ofl-proline to pyrroline-2-carboxylate

Author:

Biancalana Lorenzo1234,Tuci Giada1234,Piccinelli Fabio5674,Marchetti Fabio1234ORCID,Bortoluzzi Marco89104,Pampaloni Guido1234ORCID

Affiliation:

1. University of Pisa

2. Dipartimento di Chimica e Chimica Industriale

3. I-56124 Pisa

4. Italy

5. University of Verona

6. Solid State Chemistry Laboratory-DB

7. Verona

8. Ca’ Foscari University of Venice

9. Dipartimento di Scienze Molecolari e Nanosistemi

10. I-30175 Mestre (Venezia)

Abstract

The unusual, one pot conversion ofl-proline to pyrroline-2-carboxylate, using simple V(v) species (NH4VO3or V2O5) as oxidants in basic water medium, is described. No reaction was observed with primary and tertiary α-amino acids.

Funder

Università di Pisa

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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