Carbonatation of [ethylene–glycidyl methacrylate]-based copolymers with carbon dioxide as a reagent: from batch to solvent-free reactive extrusion-Reference-Cited by-同舟云学术

Carbonatation of [ethylene–glycidyl methacrylate]-based copolymers with carbon dioxide as a reagent: from batch to solvent-free reactive extrusion

Published:2023 Issue:16 Volume:25 Page:6355-6364
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Guerdener Bruno¹²³^ORCID,Ayzac Virgile¹,Norsic Sébastien¹,Besognet Paul³,Bounor-Legaré Véronique²,Monteil Vincent¹^ORCID,Dufaud Véronique¹^ORCID,Raynaud Jean¹^ORCID,Chalamet Yvan³

Affiliation:

1. Univ. Lyon, Université Claude Bernard Lyon 1, CPE Lyon, CNRS, UMR 5128, Catalysis, Polymerization, Processes and Materials (CP2M), 43 Bd du 11 novembre 1918, 69616 Villeurbanne cedex, France

2. Univ. Lyon, CNRS, Université Claude Bernard Lyon 1, INSA Lyon, Université Jean Monnet, UMR 5223, Ingénierie des Matériaux Polymères, F-69622 Villeurbanne cedex, France

3. Univ. Lyon, CNRS, Université Claude Bernard Lyon 1, INSA Lyon, Université Jean Monnet, UMR 5223, Ingénierie des Matériaux Polymères, F-42023 Saint-Etienne cedex 2, France

Abstract

The carbonatation of semi-crystalline [ethylene–glycidyl methacrylate] copolymers was achieved in batch and solvent-free reactive extrusion processes. Using CO2as reagent and ammonium salts as catalysts, we turn the epoxides into cyclic carbonates.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/GC/D3GC01127E

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