Enantioselective total synthesis of parnafungin A1 and 10a-epi-hirtusneanine
Author:
Affiliation:
1. State Key Laboratory of Bio-Organic and Natural Products Chemistry
2. Center for Excellence in Molecular Synthesis
3. Shanghai Institute of Organic Chemistry
4. University of Chinese Academy of Sciences
5. Shanghai 200032
Abstract
The first, enantioselective total synthesis of the heterodimeric biaryl antifungal natural product parnafungin A1 as well as 10a-epi-hirtusneanine is accomplished, using a cross-coupling strategy to construct their sterically hindered biaryl cores.
Funder
National Natural Science Foundation of China
Chinese Academy of Sciences
Science and Technology Commission of Shanghai Municipality
K. C. Wong Education Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02919C
Reference43 articles.
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5. Modular Syntheses of Diversonol-Type Tetrahydroxanthone Mycotoxins: Blennolide C (epi-Hemirugulotrosin A) and Analogues
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