Direct oxide transfer from an η2-keto ligand to generate a cobalt PCcarbeneP(O) pincer complex-Reference-Cited by-同舟云学术

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Direct oxide transfer from an η2-keto ligand to generate a cobalt PCcarbeneP(O) pincer complex

Published:2019 Issue:27 Volume:48 Page:9920-9924
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sung Simon¹²³⁴^ORCID,Tinnermann Hendrik¹²³⁴,Krämer Tobias¹⁵⁶⁷^ORCID,Young Rowan D.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. National University of Singapore

3. Singapore 117543

4. Singapore

5. Maynooth University

6. Maynooth

7. Ireland

Abstract

We report the direct carbonyl cleavage in a κ³-P′,(η²-C,O),P′′ ligand by a monomeric cobalt centre through metal–ligand cooperativity.

Funder

National University of Singapore

Ministry of Education - Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02313E

Reference53 articles.

1. Reflections on the chemistry of the Fischer–Tropsch synthesis

2. Cobalt Catalyzed Fischer–Tropsch Synthesis: Perspectives Opened by First Principles Calculations

3. Some Understanding of Fischer–Tropsch Synthesis from Density Functional Theory Calculations

4. A new look at the McMurry reaction

5. Oxidative addition of cyclopentanone to WCl2(PMePh2)4 to give a tungsten(VI) oxo-alkylidene complex

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3. Carbene Character in a Series of Neutral PC_carbeneP Cobalt(I) Complexes: Radical Carbenes versus Nucleophilic Carbenes;Organometallics;2022-01-24

4. Nonpalindromic Rhodium PCcarbeneP Pincer Complexes Featuring Electron-Deficient Phosphino Substituents;Organometallics;2021-12-09

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