Competing mechanisms for the reaction of dichloropropynylborane with 2-tert-butylbutadiene. Diels–Alder reaction versus alkynylboration-Reference-Cited by-同舟云学术

Competing mechanisms for the reaction of dichloropropynylborane with 2-tert-butylbutadiene. Diels–Alder reaction versus alkynylboration

Published:2015 Issue:86 Volume:5 Page:70147-70155
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Vallejos Margarita M.¹²³⁴⁵,Pellegrinet Silvina C.⁶⁷⁸⁹¹⁰

Affiliation:

1. Área de Química Orgánica

2. Departamento de Química

3. Facultad de Ciencias Exactas y Naturales y Agrimensura

4. Universidad Nacional del Nordeste

5. 3400 Corrientes

6. Instituto de Química Rosario (CONICET)

7. Facultad de Ciencias Bioquímicas y Farmacéuticas

8. Universidad Nacional de Rosario

9. Rosario 2000

10. Argentina

Abstract

Density functional theory and the quantum theory of atoms in molecules approach were used to study two competing process: the Diels–Alder reaction and the 1,4-alkynylboration.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA12903F

Reference51 articles.

1. Boron-Substituted Building Blocks in Diels-Alder and Other Cycloaddition Reactions

2. A Two-Step Reaction Sequence for the Syntheses of Tetrahydronaphthalenes

3. Alkynylboronic Esters as Efficient Dienophiles in Cobalt-Catalyzed Diels–Alder Reactions

4. D. G. Hall , Boronic acids: preparation and applications in organic synthesis, medicine and materials, Wiley-VCH, Weinheim, 2nd completely rev. edn, 2011

5. A Mechanistic Study of the Lewis Base-Directed Cycloaddition of 2-Pyrones and Alkynylboranes

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