A highly contorted push–pull naphthalenediimide dimer and evidence of intramolecular singlet exciton fission-Reference-Cited by-同舟云学术

A highly contorted push–pull naphthalenediimide dimer and evidence of intramolecular singlet exciton fission

Published:2022 Issue:39 Volume:13 Page:11506-11512
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Bansal Deepak¹^ORCID,Kundu Arup²^ORCID,Singh Vijay Pal¹,Pal Arun K.³^ORCID,Datta Ayan³^ORCID,Dasgupta Jyotishman²^ORCID,Mukhopadhyay Pritam¹^ORCID

Affiliation:

1. School of Physical Sciences, Jawaharlal Nehru University, New Delhi 110067, India

2. Department of Chemical Sciences, Tata Institute of Fundamental Research, Mumbai 400005, India

3. School of Chemical Sciences, Indian Association for the Cultivation of Science, Kolkata 700032, West Bengal, India

Abstract

We report for the first-time intramolecular singlet fission (SF) in the naphthalenediimide (NDI) scaffold constrained in a cyclophane architecture, while individually the NDI units does not satisfy the requisite energy criterion for SF.

Funder

Science and Engineering Research Board

Department of Atomic Energy, Government of India

Department of Science and Technology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC04187A

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1. Singlet Fission

2. Laser Generation of Excitons and Fluorescence in Anthracene Crystals

3. Singlet fission of tetracene during electron transfer reaction

4. Triplet Pair States in Singlet Fission

5. External Quantum Efficiency Above 100% in a Singlet-Exciton-Fission–Based Organic Photovoltaic Cell

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