The tipping point of the inert pair effect: experimental and computational comparison of In(i) and Sn(ii) bis(imino)pyridine complexes-Reference-Cited by-同舟云学术

The tipping point of the inert pair effect: experimental and computational comparison of In(i) and Sn(ii) bis(imino)pyridine complexes

Published:2014 Issue:2 Volume:43 Page:690-697
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jurca Titel¹²³⁴,Hiscock Lana K.⁵⁶⁷⁴,Korobkov Ilia¹²³⁴,Rowley Christopher N.⁵⁶⁷⁴,Richeson Darrin S.¹²³⁴

Affiliation:

1. Department of Chemistry and the Centre for Catalysis Research and Innovation

2. University of Ottawa

3. Ottawa

4. Canada

5. Department of Chemistry

6. Memorial University of Newfoundland

7. St. John's

Abstract

The autoionization reaction of neutral bis(imino)pyridine and SnX₂ led to three compounds [{ArNCPh}₂(NC₅H₃)]SnX⁺SnX₃⁻ (Ar = 2,6-(2,5-^tBu₂C₆H₃), X = Cl, Br; Ar = 2,6-(2,6-Me₂C₆H₃), X = Cl) which display, within the same species, cations and anions possessing Sn(ii) centers.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT52227J

Reference41 articles.

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2. Harnessing Low-Valent Metal Centers through Non-Bonding Orbital Interactions

3. A Cryptand-Encapsulated Germanium(II) Dication

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