Surface modified CFx cathode material for ultrafast discharge and high energy density

Author:

Dai Yang12345,Cai Sendan12345,Wu Lijun678,Yang Weijing12,Xie Jingying1292,Wen Wen1011,Zheng Jin-Cheng12131415,Zhu Yimei678

Affiliation:

1. Shanghai Institute of Space Power Sources

2. Shanghai 200245, China

3. Department of Chemical Engineering

4. School of Environmental and Chemical Engineering

5. Shanghai University

6. Condensed Matter Physics & Materials Science Department

7. Brookhaven National Laboratory

8. Upton, USA

9. Shanghai Engineering Center for Power and Energy Storage Systems

10. BL14B1 Shanghai Synchrotron Radiation Facility

11. Shanghai, China

12. Department of Physics

13. Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry

14. Xiamen University

15. Xiamen 361005, China

Abstract

An effective de-fluorination method is developed to modify CFx cathodes through a hydrothermal process and it greatly improves the capacity performance and rate capability of CFx by removal of surface ionic transport barriers. A capacity of 500 mA h g−1 and a maximum power density of 48 400 W kg−1 were achieved at an ultrafast rate of 30 C.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Reference19 articles.

1. N. Watanabe , T.Nakajima and H.Touhara, Graphite Fluorides, Elsevier, Amsterdam, 1988

2. A. Hamwi , K.Guerin and M.Dubois, Fluorinated Materials for Energy Conversion, Elsevier, Oxford, UK, 2005

3. Li–O2 and Li–S batteries with high energy storage

4. Applicative performances of fluorinated carbons through fluorination routes: A review

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