Hydrosilylative reduction of primary amides to primary amines catalyzed by a terminal [Ni

Hydrosilylative reduction of primary amides to primary amines catalyzed by a terminal [Ni–OH] complex

Published:2021 Issue:73 Volume:57 Page:9204-9207
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Pandey Pragati¹,Bera Jitendra K.¹^ORCID

Affiliation:

1. Department of Chemistry and Center for Environmental Science and Engineering, Indian Institute of Technology Kanpur, Kanpur 208016, India

Abstract

A terminal [Ni–OH] complex, stabilized by triflamide-tethered NHC ligands, selectively catalyses the deoxygenative reduction of primary amides to primary amines using phenylsilane as the reductant, without proceeding via a nitrile intermediate.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC03537A

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