Improved quantum yield in geometrically constrained tetraphenylethylene-based metal–organic frameworks

Author:

Stawiasz Katherine J.12ORCID,Deneff Jacob I.3,Reyes Raphael A.3,Woods Toby J.4ORCID,Rohwer Lauren E. S.5,Valdez Nichole6,Rodriguez Mark A.6ORCID,Lawal Abdul2,Moore Jeffrey S.12ORCID,Sava Gallis Dorina F.3ORCID

Affiliation:

1. Beckman Institute for Advanced Science and Technology, University of Illinois at Urbana–Champaign, Urbana, IL 61801, USA

2. Department of Chemistry, University of Illinois at Urbana–Champaign, Urbana, IL 61801, USA

3. Nanoscale Sciences Department, Sandia National Laboratories, Albuquerque, NM 87185, USA

4. George L. Clark X-Ray Facility and 3M Materials Laboratory, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA

5. Advanced Packaging/Integration Department, Sandia National Laboratories, Albuquerque, NM 87185, USA

6. Materials Characterization and Performance Department, Sandia National Laboratories, Albuquerque, NM 87185, USA

Abstract

Linker rigidification via incorporation into two new MOF materials results in a 2.5× increase in quantum yield compared to the linker alone. Furthermore, optical properties of the resulting materials are displaying solvatochromatic effects.

Funder

Laboratory Directed Research and Development

U.S. Department of Defense

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Cited by 2 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3