Alkoxycarbonylation of α,β-unsaturated amides catalyzed by palladium(ii) complexes: a DFT study of the mechanism-Reference-Cited by-同舟云学术

Alkoxycarbonylation of α,β-unsaturated amides catalyzed by palladium(ii) complexes: a DFT study of the mechanism

Published:2016 Issue:10 Volume:6 Page:8440-8448
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Suleiman Rami¹²³⁴,Polo Victor⁵⁶⁷⁸⁹,El Ali Bassam¹⁰²³⁴

Affiliation:

1. Center of Research Excellence in Corrosion

2. King Fahd University of Petroleum & Minerals (KFUPM)

3. Dhahran 31261

4. Saudi Arabia

5. Departamento de Química Física Universidad de Zaragoza e Instituto de Biocomputación y Física de Sistemas Complejos (BIFI)

6. 50009 Zaragoza

7. Spain

8. CSIC

9. Instituto de Química Física Rocasolano

10. Chemistry Department

Abstract

Two mechanisms, hydride and alkoxy, were proposed for the alkoxycarbonylation of α,β-unsaturated amides. These are studied with the use of DFT computations.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA26600A

Reference49 articles.

1. L. Kollár , Modern Carbonylation Methods, Wiley-VCH, 2008

2. M. Beller , Catalytic Carbonylation Reactions, Springer, Berlin, 2006

3. Catalytic and regioselective synthesis of gem- or trans-?,?-unsaturated amides by carbonylation of alkyl alkynes with aniline derivatives by palladium(II) and phosphine

4. Palladium-catalyzed selective alkoxycarbonylation of α,β-unsaturated amides: a novel approach toward new ω-amido esters and N-substituted cyclic succinimides

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