Restricted access to a conical intersection to explain aggregation induced emission in dimethyl tetraphenylsilole

Author:

Peng Xing-Liang12345,Ruiz-Barragan Sergi6789,Li Ze-Sheng12345,Li Quan-Song12345,Blancafort Lluís10111213

Affiliation:

1. Key Laboratory of Cluster Science of Ministry of Education

2. School of Chemistry

3. Beijing Institute of Technology

4. 100081 Beijing

5. China

6. Japan Atomic Energy Agency

7. Tokyo University

8. Kashiwa

9. Japan

10. Institut de Química Computacional i Catàlisi and Departament de Química

11. Universitat de Girona

12. 17071 Girona

13. Spain

Abstract

Aggregation-induced emission of dimethyl tetraphenylsilole is due to restricted access to a conical intersection. The intersection allows for radiationless decay in solution but is not reachable in the aggregate phase.

Funder

Ministerio de Ciencia e Innovación

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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