Flow chemistry-enabled studies of rhodium-catalyzed hydroformylation reactions
Author:
Affiliation:
1. Department of Chemical and Biomolecular Engineering
2. North Carolina State University
3. Raleigh
4. USA
5. Department of Chemical Engineering
6. Massachusetts Institute of Technology
7. Cambridge
8. Eastman Chemical Company
9. Kingsport
Abstract
We present an autonomous microscale flow chemistry platform for high-throughput fundamental and applied studies of homogeneous hydroformylation reactions.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC04650F
Reference36 articles.
1. Monometallic and mixed-valence bimetallic Rh(I/III) complexes: Synthesis, structure, electrochemistry and application in 1-octene hydroformylation
2. Selective hydroformylation of 1-hexene to branched aldehydes using rhodium complex of modified bulky phosphine and phosphite ligands
3. Hydroformylation of 1-dodecene using Rh-TPPTS in a microemulsion
4. Synthesis and characterization of novel rhodium and ruthenium based iminopyridyl complexes and their application in 1-octene hydroformylation
5. Xantphos doped Rh/POPs-PPh3 catalyst for highly selective long-chain olefins hydroformylation: Chemical and DFT insights into Rh location and the roles of Xantphos and PPh3
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