Circular dichroism spectroscopy of catalyst preequilibrium in asymmetric autocatalysis of pyrimidyl alkanol-Reference-Cited by-同舟云学术

Circular dichroism spectroscopy of catalyst preequilibrium in asymmetric autocatalysis of pyrimidyl alkanol

Published:2021 Issue:85 Volume:57 Page:11209-11212
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Matsumoto Arimasa¹^ORCID,Tanaka Ayame¹,Kaimori Yoshiyasu²,Hara Natsuki²,Mikata Yuji¹^ORCID,Soai Kenso²^ORCID

Affiliation:

1. Department of Chemistry, Biology, and Environmental Science, Nara Women's University, Kita-Uoya Nishi-machi, Nara, 630-8506, Japan

2. Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan

Abstract

Circular dichroism spectroscopic analysis of the asymmetric autocatalytic reaction of pyrimidyl alkanol reveals the dimeric and tetrameric equilibria of the alkoxide catalyst in the solution state.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC04206H

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