Iron-promoted dealkylative carbene aminocyclization of δ-arylamino-α-diazoesters-Reference-Cited by-同舟云学术

Iron-promoted dealkylative carbene aminocyclization of δ-arylamino-α-diazoesters

Published:2021 Issue:6 Volume:50 Page:2167-2176
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Solé Daniel¹²³⁴⁵^ORCID,Amenta Arianna¹²³⁴⁵,Campos Cristina¹²³⁴⁵,Fernández Israel⁶⁷⁸⁹⁵^ORCID

Affiliation:

1. Laboratori de Química Orgànica

2. Facultat de Farmàcia i Ciències de l'Alimentació

3. Universitat de Barcelona

4. 08028 Barcelona

5. Spain

6. Departamento de Química Orgánica I and Centro de Innovación en Química Avanzada (ORFEO–CINQA)

7. Facultad de Ciencias Químicas

8. Universidad Complutense de Madrid

9. 28040 Madrid

Abstract

In the presence of substoichiometric amounts of FeBr₂, δ-arylamino-α-diazoesters undergo dealkylative aminocyclization to give N-aryl proline derivatives through a Fe(ii)–carbene intermediate.

Funder

Ministerio de Economía y Competitividad

Federación Española de Enfermedades Raras

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04373G

Reference55 articles.

1. Ylide formation from the reaction of carbenes and carbenoids with heteroatom lone pairs

2. Modern Organic Synthesis with α-Diazocarbonyl Compounds

3. α,β-Unsaturated Diazoketones as Useful Platforms in the Synthesis of Nitrogen Heterocycles

4. Nitrogen, Oxygen and Sulfur Ylide Chemistry: A Practical Approach in Chemistry , ed. C. J. Stephen , Oxford University Press , Oxford , 2002

5. Rh-Catalyzed Chemoselective [4 + 1] Cycloaddition Reaction toward Diverse 4-Methyleneprolines

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Melding of Experiment and Theory Illuminates Mechanisms of Metal-Catalyzed Rearrangements: Computational Approaches and Caveats;Synthesis;2021-07-14