Opening the Egg Box: NMR spectroscopic analysis of the interactions between s-block cations and kelp monosaccharides-Reference-Cited by-同舟云学术

Opening the Egg Box: NMR spectroscopic analysis of the interactions between s-block cations and kelp monosaccharides

Published:2021 Issue:38 Volume:50 Page:13246-13255
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Rowbotham Jack S.¹²^ORCID,Christopher Greenwell H.¹³^ORCID,Dyer Philip W.¹^ORCID

Affiliation:

1. Department of Chemistry, Durham University, South Road, Durham, DH1 3LE, UK

2. Current address: Department of Chemistry, Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK

3. Department of Earth Sciences, Durham University, South Road, Durham, DH1 3LE, UK

Abstract

The α-form of kelp-derived monosaccharide l-guluronate (α-GulA) has a unique axial-equatorial-axial (ax–eq–ax) arrangement of hydroxyl groups that can coordinate to divalent cations (e.g. Ca2+), stabilising the structure relative to its β-anomer.

Funder

Engineering and Physical Sciences Research Council

Durham University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04375C

Reference77 articles.

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2. Structural components of alginic acid. II. The crystalline structure of poly-?-L-guluronic acid. Results of X-ray diffraction and polarized infrared studies