Bifunctional conjugated polymer photocatalysts for visible light water oxidation and CO2 reduction: function- and site-selective hybridisation of Ru(ii) complex catalysts

Author:

Ishihara Kotaro1,Nakada Akinobu12ORCID,Suzuki Hajime1ORCID,Tomita Osamu1ORCID,Nozawa Shunsuke3,Saeki Akinori4ORCID,Abe Ryu1ORCID

Affiliation:

1. Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan

2. Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

3. Photon Factory (PF), Institute of Materials Structure Science (IMSS), High Energy Accelerator Research Organization (KEK), Tsukuba, Ibaraki 305-0801, Japan

4. Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

Abstract

Function-/site-selective hybridisation of two specific Ru(ii) complex catalysts on donor–acceptor conjugated polymers enables bifunctional visible-light water oxidation and CO2 reduction.

Funder

Precursory Research for Embryonic Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

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