Site-specific orthometallation via C–H bond activation and syntheses of ruthenium(iii) organometallics: studies on nitric oxide (NO) reactivity and photorelease of coordinated NO-Reference-Cited by-同舟云学术

Site-specific orthometallation via C–H bond activation and syntheses of ruthenium(iii) organometallics: studies on nitric oxide (NO) reactivity and photorelease of coordinated NO

Published:2016 Issue:76 Volume:6 Page:72096-72106
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Kumar Rajan¹²³⁴,Kumar Sushil¹²³⁴,Bala Manju¹²³⁴,Ratnam Anand¹²³⁴,Singh U. P.¹²³⁴,Ghosh Kaushik¹²³⁴

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Roorkee

3. Roorkee – 247667

4. India

Abstract

σ-Aryl ruthenium(iii) complexes were synthesized by C–H bond activation and organometallic nitrosyl complexes were synthesized and characterized by spectroscopy and crystal structure. Coordinated NO molecule was found to be photolabile.

Funder

Council for Scientific and Industrial Research

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA17223G

Reference57 articles.

1. Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

2. Ru-, Rh-, and Pd-Catalyzed C−C Bond Formation Involving C−H Activation and Addition on Unsaturated Substrates: Reactions and Mechanistic Aspects

3. Cyclometalated ruthenium chromophores for the dye-sensitized solar cell