FeCl3-catalyzed oxidative amidation of benzylic C–H bonds enabled by a photogenerated chlorine-radical

Author:

Yang Yingying1,Yu Xianglin1,He Na1,Huang Xinxiang1,Song Xizhong2,Chen Jingbo1ORCID,Lin Jun1ORCID,Jin Yi1ORCID

Affiliation:

1. Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, Yunnan Provincial Center for Research & Development of Natural Products, School of Pharmacy, Yunnan University, Kunming, 650091, P. R. China

2. Jianxi Zhiheng Hall Chinese Herbal Medicine Co. Ltd., Jianxi, 331200, P. R. China

Abstract

Iron-catalyzed benzylic C–H oxidative amidation reactions via photoinduced ligand-to-metal charge transfer (LMCT) for the construction of amide and quinazolinone derivatives.

Funder

National Natural Science Foundation of China

People's Government of Yunnan Province

Yunnan University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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