The AlAl triple bond in Al2X5+ and Al2X62+ (X = Li, Na) clusters with multiple alkali metal coordination-Reference-Cited by-同舟云学术

The AlAl triple bond in Al2X5+ and Al2X62+ (X = Li, Na) clusters with multiple alkali metal coordination

Published:2020 Issue:48 Volume:44 Page:21119-21124
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Liu Yingying¹²³⁴⁵,Zhu Changyan¹²³⁴⁵,Wen Chaoxia¹²³⁴⁵,Zhang Min¹²³⁴⁵^ORCID,Geng Yun¹²³⁴⁵^ORCID,Liu Xingman⁶⁷⁸⁹,Su Zhongmin¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Functional Material Chemistry

2. Faculty of Chemistry & National & Local United Engineering Laboratory for Power Battery

3. Northeast Normal University

4. Changchun 130024

5. P. R. China

6. College of Chemistry and Chemical Engineering

7. Ningxia University

8. Yinchuan 750021

9. China

Abstract

The AlAl triple bond does not change obviously with the increase in the number of Li⁺ or Na⁺ and [AlAl]⁴⁻ is the core to stabilize these clusters and its stability is hard to be affected by the numbers and positions of the Li⁺ or Na⁺.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ04819D

Reference52 articles.

1. Analogies between Group 13 metal clusters in organometallic and intermetallic structures

2. Homonuclear multiple bonding in heavier main group elements