Dynamics of the efficient cyclometalation of the undercoordinated organoplatinum complex [Pt(COD)(neoPh)]+ (neoPh = 2-methyl-2-phenylpropyl)-Reference-Cited by-同舟云学术

Dynamics of the efficient cyclometalation of the undercoordinated organoplatinum complex [Pt(COD)(neoPh)]+ (neoPh = 2-methyl-2-phenylpropyl)

Published:2020 Issue:44 Volume:44 Page:19238-19249
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Neugebauer Michael¹²³⁴⁵,Schmitz Simon¹²³⁴⁵^ORCID,Brünink Dana⁶⁷⁸⁵,Doltsinis Nikos L.⁶⁷⁸⁵^ORCID,Klein Axel¹²³⁴⁵^ORCID

Affiliation:

1. University of Cologne

2. Department of Chemistry

3. Institute for Inorganic Chemistry

4. D-50939 Cologne

5. Germany

6. Westfälische Wilhelms-Universität Münster

7. Institut für Festkörpertheorie and Center for Multiscale Theory and Computation

8. 48149 Münster

Abstract

The cyclometalation reaction of [Pt(COD)(κ¹-neoPh)]⁺ (neoPh = 2-methyl-2-phenylpropyl) to [Pt(COD)(κ²-neoPh)] was studied experimentally and mechanistically using DFT and MD simulations.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ04811A

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