Copper-ion assisted photochemical vapor generation of bromide and bromate-Reference-Cited by-同舟云学术

Copper-ion assisted photochemical vapor generation of bromide and bromate

Published:2021 Issue:6 Volume:36 Page:1235-1243
ISSN:0267-9477
Container-title:Journal of Analytical Atomic Spectrometry
language:en
Short-container-title:J. Anal. At. Spectrom.

Author:

de Oliveira Richard M.¹²³⁴^ORCID,Borges Daniel L. G.¹²³⁴^ORCID,Grinberg Patricia⁵⁶⁷⁸⁹^ORCID,Mester Zoltan⁵⁶⁷⁸⁹^ORCID,Sturgeon Ralph E.⁵⁶⁷⁸⁹^ORCID

Affiliation:

1. Universidade Federal de Santa Catarina (UFSC)

2. Departamento de Química

3. Florianópolis

4. Brazil

5. National Research Council of Canada

6. Metrology

7. Inorganic Chemical Metrology

8. Ottawa

9. Canada

Abstract

Efficient photochemical vapor generation of CH₃Br from bromide and bromate using a medium consisting of 2% acetic acid and 10 mg L⁻¹ Cu²⁺ is demonstrated. Mechanisms involving a Cu–Br complex are discussed.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Publisher

Royal Society of Chemistry (RSC)

Subject

Spectroscopy,Analytical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/JA/D1JA00094B

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