Modulating CsPbBr3 nanocrystals encapsulated in PCN-224(Zr) for boosting full-spectrum-driven CO2 reduction: S-scheme transfer, photothermal-synergistic effect, and DFT calculations

Author:

Chen Yan-He1,Shen Jin-Qiu1,Chen Xiao-Lu1,Tang Luobing2,Zhang Na2,Zhang Jian-Yong1ORCID,Liu Zhen-Jiang1ORCID

Affiliation:

1. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, P. R. China

2. School of Materials Science and Engineering, Shanghai Institute of Technology, Shanghai 201418, P. R. China

Abstract

CsPbBr3@PCN-224(Zr) heterojunction exhibits enhanced full-spectrum-driven photocatalytic CO2RR activity promoted by S-scheme transfer and photothermal synergism with the highest CO yield and total electron consumption of 73.85 and 178.9 μmol g−1 h−1.

Funder

National Natural Science Foundation of China

Science and Technology Commission of Shanghai Municipality

Publisher

Royal Society of Chemistry (RSC)

Subject

Energy Engineering and Power Technology,Fuel Technology,Renewable Energy, Sustainability and the Environment

Reference38 articles.

1. The technological and economic prospects for CO2 utilization and removal

2. IPCC , Climate Change 2014-Impacts, Adaptation and Vulnerability: Regional Aspects , Cambridge University Press , 2014

3. National Ocean and Atmospheric Administration (NOAA) and National Centers for Environmental Information , Global Climate Change Indicators , 2020 , https://www.ncdc.noaa.gov/monitoring-references/faq/indicators.php#warming-climate

4. Critical Aspects and Recent Advances in Structural Engineering of Photocatalysts for Sunlight‐Driven Photocatalytic Reduction of CO 2 into Fuels

5. From Solar Energy to Fuels: Recent Advances in Light‐Driven C 1 Chemistry

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