Supramolecular polymerization of electronically complementary linear motifs: anti-cooperativity by attenuated growth

Author:

Dorca Yeray1,Naranjo Cristina1ORCID,Ghosh Goutam2ORCID,Soberats Bartolomé3ORCID,Calbo Joaquín4ORCID,Ortí Enrique4ORCID,Fernández Gustavo2ORCID,Sánchez Luis1ORCID

Affiliation:

1. Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Ciudad Universitaria, s/n, 28040, Madrid, Spain

2. Organisch-Chemisches Institut Westfälische Wilhelms, Universität Münster, Corrensstraße 36, 48149 Münster, Germany

3. Department of Chemistry, University of the Balearic Islands, Cra. Valldemossa, Km. 7.5, 07122, Palma de Mallorca, Spain

4. Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, C/Catedrático José Beltrán, 2, 46980 Paterna, Spain

Abstract

The anti-cooperative supramolecular polymerization of compounds 1 and 2, in which the formation of the nuclei is favoured over the growth of the aggregate, is investigated. Despite this anti-cooperativity 1 and 2 can afford co-assembled aggregates.

Funder

Ministerio de Ciencia e Innovación

Generalitat Valenciana

Comunidad de Madrid

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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