Interaction of anions with the surface of a coordination cage in aqueous solution probed by their effect on a cage-catalysed Kemp elimination-Reference-Cited by-同舟云学术

Interaction of anions with the surface of a coordination cage in aqueous solution probed by their effect on a cage-catalysed Kemp elimination

Published:2021 Issue:44 Volume:12 Page:14781-14791
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ludden Michael D.¹,Taylor Christopher G. P.¹^ORCID,Tipping Max B.¹,Train Jennifer S.²,Williams Nicholas H.²^ORCID,Dorrat Jack C.³,Tuck Kellie L.³^ORCID,Ward Michael D.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Warwick, Coventry CV4 7AL, UK

2. Department of Chemistry, University of Sheffield, Sheffield S3 7HF, UK

3. School of Chemistry, Monash University, Melbourne, VIC3800, Australia

Abstract

A cage-catalysed Kemp elimination reaction of 5-nitro-1,2-benzisoxazole (NBI) with hydroxide to give 2-cyano-4-nitrophenolate (CNP) as the product is sensitive to binding of different types of anion to the cage surface.

Funder

Engineering and Physical Sciences Research Council

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC04887B

Reference80 articles.

1. Recent Developments in the Preparation and Chemistry of Metallacycles and Metallacages via Coordination

2. Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials