A solvent- and temperature-dependent intramolecular equilibrium of diamagnetic and paramagnetic states in Co complexes bearing triaryl amines-Reference-Cited by-同舟云学术

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A solvent- and temperature-dependent intramolecular equilibrium of diamagnetic and paramagnetic states in Co complexes bearing triaryl amines

Published:2018 Issue:37 Volume:47 Page:13180-13189
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Schnaubelt Linda¹²³⁴⁵,Petzold Holm¹²³⁴⁵^ORCID,Dmitrieva Evgenia⁶⁷⁸⁹,Rosenkranz Marco⁶⁷⁸⁹,Lang Heinrich¹²³⁴⁵^ORCID

Affiliation:

1. Technische Universität Chemnitz

2. Faculty of Natural Sciences

3. Institute of Chemistry

4. Inorganic Chemistry

5. 09107 Chemnitz

6. Center of Spectroelectrochemistry

7. Leibniz Institute for Solid State and Materials Research (IFW Dresden)

8. 01069 Dresden

9. Germany

Abstract

Synthesis of Co²⁺ complexes bearing redox-active triaryl amines, exhibiting thermochromic redox equilibrium after one-electron oxidation.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT02538J

Reference79 articles.

1. Photoinduced processes in dyads and triads containing a ruthenium(II)-bis(terpyridine) photosensitizer covalently linked to electron donor and acceptor groups

2. Triphenylamine-Modified Ruthenium(II) Terpyridine Complexes: Enhancement of Light Absorption by Conjugated Bridging Motifs

3. A Combined Experimental and Computational Study of Linear Ruthenium(II) Coordination Oligomers with End-Capping Organic Redox Sites: Insight into the Light Absorption and Charge Delocalization

4. A Bis(terpyridine)ruthenium Complex with Three Redox-Active Amine Sites: Electrochemical, Optical, and Computational Studies

5. Mixed valency in ruthenium complexes—Coordinative aspects

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1. Water-Mediated Charge Transfer and Electron Localization in a Co₃Fe₂ Cyanide-Bridged Trigonal Bipyramidal Complex;Journal of the American Chemical Society;2024-03-13

2. Multistate redox processes of structurally asymmetric diamines with a cyclometalated ruthenium bridge;Journal of Organometallic Chemistry;2021-07

3. Switching metal complexes via intramolecular electron transfer: connections with solvatochromism;Inorganic Chemistry Frontiers;2021

4. Co(cyclam) Complexes of Triarylamine-acetylide: Structural and Spectroscopic Properties and DFT Analysis;Organometallics;2020-08-25

5. Tailoring of the Frontier Orbital Character in Co 2+/3+ Complexes with Triarylamine Substituted Terpyridine Ligands;European Journal of Inorganic Chemistry;2019-02-10

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