A nonconjugated radical polymer with stable red luminescence in the solid state

Author:

Wang Zhaoyu1ORCID,Zou Xinhui1,Xie Yi2,Zhang Haoke1,Hu Lianrui1,Chan Christopher C. S.1,Zhang Ruoyao1,Guo Jing3,Kwok Ryan T. K.1,Lam Jacky W. Y.1,Williams Ian D.1ORCID,Zeng Zebing3ORCID,Wong Kam Sing1,Sherrill C. David2,Ye Ruquan4ORCID,Tang Ben Zhong5ORCID

Affiliation:

1. Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Institute for Advanced Study, Guangdong-Hong Kong-Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials, Department of Chemical and Biological Engineering, and Department of Physics, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China

2. Center for Computational Molecular Science and Technology, School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia, 30332-0400, USA

3. State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, P. R. China

4. Department of Chemistry, State Key Laboratory of Marine Pollution, City University of Hong Kong, Hong Kong, China

5. School of Science and Engineering, Shenzhen Institute of Aggregate Science and Technology, The Chinese University of Hong Kong, Shenzhen, Guangdong, 518172, China

Abstract

A radical polymer without any delocalized π-stabilization was synthesized from a classical chromophore quencher, TEMPO, which surprisingly shows red emission.

Funder

National Natural Science Foundation of China

Research Grants Council, University Grants Committee

University Grants Committee

Natural Science Foundation of Guangdong Province

Innovation and Technology Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrical and Electronic Engineering,Process Chemistry and Technology,Mechanics of Materials,General Materials Science

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