Operando soft X-ray emission spectroscopy of the Fe2O3 anode to observe the conversion reaction

Author:

Asakura Daisuke12345ORCID,Nanba Yusuke1234ORCID,Okubo Masashi1234ORCID,Niwa Hideharu67849ORCID,Kiuchi Hisao107114,Miyawaki Jun67849,Oshima Masaharu97124,Hosono Eiji12345ORCID,Harada Yoshihisa5131446ORCID

Affiliation:

1. Research Institute for Energy Conservation

2. National Institute of Advanced Industrial Science and Technology (AIST)

3. Ibaraki 305-8568

4. Japan

5. AIST-UTokyo Advanced Operando-Measurement Open Innovation Laboratory (OPERANDO-OIL)

6. Institute for Solid State Physics

7. The University of Tokyo

8. Chiba 277-8581

9. Synchrotron Radiation Research Organization

10. Department of Applied Chemistry

11. Tokyo 113-8656

12. Hyogo 679-5148

13. AIST

14. Chiba 277-8565

Abstract

Drastic electronic-structure changes in an Fe2O3 thin film anode for a Li-ion battery during discharge (lithiation) and charge (delithiation) processes were observed using operando Fe 2p soft X-ray emission spectroscopy (XES).

Funder

Ministry of Economy, Trade and Industry

Japan Society for the Promotion of Science

University of Tokyo

High Energy Accelerator Research Organization

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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