Multipodal coordination and mobility of molecular cations inside the macrocycle valinomycin-Reference-Cited by-同舟云学术

Multipodal coordination and mobility of molecular cations inside the macrocycle valinomycin

Published:2020 Issue:35 Volume:22 Page:19725-19734
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Avilés-Moreno Juan Ramón¹²³⁴,Gámez Francisco¹²³⁴^ORCID,Berden Giel⁵⁶⁷⁸⁹^ORCID,Martens Jonathan⁵⁶⁷⁸⁹,Oomens Jos⁵⁶⁷⁸⁹^ORCID,Martínez-Haya Bruno¹⁰¹¹¹²¹³⁴^ORCID

Affiliation:

1. Department of Applied Physical Chemistry

2. Universidad Autónoma de Madrid

3. Madrid

4. Spain

5. Radboud University

6. Institute for Molecules and Materials

7. FELIX Laboratory

8. 6525ED Nijmegen

9. The Netherlands

10. Department of Physical

11. Chemical and Natural Systems

12. Universidad Pablo de Olavide

13. 41013 Seville

Abstract

Small cations (K⁺, NH₄⁺) occupy the center of the valinomycin cavity. Bulkier cations like H₄PO₄⁺ stretch the valinomycin backbone, which adopts barrel-like and funnel-like configurations, depending on the dynamically varying position of the cation.

Funder

Horizon 2020 Framework Programme

Consejería de Economía, Innovación, Ciencia y Empleo, Junta de Andalucía

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP02996C

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1. Conformational states and biological activity of cyclic peptides