Catecholase activity, DNA binding and cytotoxicity studies of a Cu(ii) complex of a pyridoxal schiff base: synthesis, X-ray crystal structure, spectroscopic, electrochemical and theoretical studies-Reference-Cited by-同舟云学术

Catecholase activity, DNA binding and cytotoxicity studies of a Cu(ii) complex of a pyridoxal schiff base: synthesis, X-ray crystal structure, spectroscopic, electrochemical and theoretical studies

Published:2016 Issue:90 Volume:6 Page:86851-86861
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Adak Piyali¹²³⁴,Ghosh Bipinbihari¹²³⁴,Bauzá Antonio¹⁵⁶⁷,Frontera Antonio¹⁵⁶⁷^ORCID,Blake Alexander J.⁸⁹¹⁰¹¹^ORCID,Corbella Montserrat¹²¹³¹⁴⁷,Das Mukhopadhyay Chitrangada¹⁵²³⁴,Chattopadhyay Shyamal Kumar¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Engineering Science and Technology

3. Shibpur

4. India

5. University of the Balearic Islands

6. 07122 Palma de Mallorca

7. Spain

8. School of Chemistry

9. The University of Nottingham

10. Nottingham NG7 2RD

11. UK

12. Department of Inorganic Chemistry

13. University of Barcelona

14. 08028 Barcelona

15. Centre for Healthcare Science and Technology

Abstract

A Cu(ii) complex, [Cu(L¹H^py)Cl]₂(ClO₄)₂, of a tridentate pyridoxal Schiff base shows exceptionally high catalytic efficiency (k_cat = 3.46 × 10⁵ h⁻¹) for catecholase activity in MeOH solution, the highest value reported in literature so far.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA14059A

Reference67 articles.

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4. Phenolase and Pectic Enzyme Activity in the Chocolate Spot Disease of Beans

5. Biochemical and spectroscopic characterization of catechol oxidase from sweet potatoes (Ipomoea batatas) containing a type-3 dicopper center1

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